monoammonium phosphate toxicity

This Safety Data Sheet was updated on the date shown and supersedes all previous versions. Toxicity Monoammonium Phosphate (7722-76-1) LC50 fish 1 155 ppm (96 h; Pimephales promelas) 12.2. But while they get the job done, they leave quite a mess behind. Epub 2017 Feb 3. Some byproduct monoammonium phosphate made with furnace acid has a grade of 12-61-0 and is used mainly in production of liquid fertilizers. stream 12.2. The crystal shape is perfect for green "emerald" crystals. Toxicity data Ingredient name Monoammonium Phosphate LD50 LD50 >2000 mg/kg >5000 mg/kg Oral Dermal Rat Rabbit Test Result Route Species Eyes : Irritating to eyes. FIRST AID MEASURES The chemical is used in animal feed, plant fertilizers, and is found in some dry chemical fire extinguishers. 1303 0 obj <>stream Ammonium dihydrogen phosphate Revision Date 23-Jan-2018 Monoammonium phosphate 7722-76-1 >95 4. Get medical attention if symptoms occur. 0 11-24 Mono Ammonium Phosphate Feed Grade Chemical Name and Synonyms C.A.S. 2B, H320 1. The toxic effect of diammonium phosphate was more pronounced than that of urea. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. ADP is a major ingredient of agricultural fertilizers and some fire extinguishers. Get medical attention if H��W�N�H}��G{�i��B�:�J�2�>0�� D" ��j� `�2��S�OU��E>��vv��. <> Several liquid ammonium phosphate fertilizer tanks have ruptured due to inadequate tank design and maintenance. Various fertilizers differ in toxicity. 1288 0 obj <>/Filter/FlateDecode/ID[<33C1B0E70CE81D4498E21C7D52E63F6B>]/Index[1271 33]/Info 1270 0 R/Length 92/Prev 183483/Root 1272 0 R/Size 1304/Type/XRef/W[1 3 1]>>stream Lee et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation. Physical Hazards: Slippery when wet. Chemosphere. Nongranular (powder) monoammonium phosphate is used in formulations for granular NP and NPK fertilizers, which it can react with additional ammonia and aid … endobj <>>> %PDF-1.5 %�� NFPA HAZARD HMIS HAZARD WHMIS HAZARD 1271 0 obj <> endobj 77, No. Ammonium nitrate, monoammonium phosphate and ammonium sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea. Irritating to skin. Persistence and degradability AGROPELL by Simplot Ammonium Phosphate Sulfate 16-20-0 with 13% Sulfur Persistence and … h�b```� �N��Al>�Fv ��,�� $��/�g� Os ? Symptoms may include nausea, vomiting and diarrhea. %�� Q�S�NՂ�K�2�x6Y��jwN��:)�bw�_��"n�� 8��$5��~j�"�0�T?��wĽ��H��H��G� Persistence and degradability 11-52-0 Monoammonium Phosphate (7783-28-0) Persistence and degradability Biodegradability in water: no data available. Monoammonium Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges, apples, cheese and yogurt. Decomposition of sodium hypochlorite takes place within a few seconds with the following salts: ammonium acetate, ammonium carbonate, ammonium nitrate, ammonium oxalate, and ammonium phosphate [Mellor 2 Supp. Inhalation : No known significant effects or critical hazards. Ammonium phosphate dry chemical fire extinguishers are an essential tool for putting out fires. Decomposes to ammonia and monoammonium phosphate at around 70 °C (158 °F). Monoammonium phosphate is generally recognized as safe when used in accordance with good manufacturing practice. Cancer Information: 2,4-D --Potassium salts have a hypothetical risk of hyperkalemia which can cause cardiac arrhythmia. Residual effects of monoammonium phosphate, gypsum and elemental sulfur on cadmium phytoavailability and translocation from soil to wheat in an effluent irrigated field. Odor: Monoammonium Phosphate has faint acid odor. 12.3. �� aB�L75�*Dh\}��((��SkC�P/Sy#��b�AπFe2,uX��Z!0�S��A�*CEb@J C�� J>�K��f0�.�;D��C �ķ �N Acute oral toxicity < 10% Acute dermal toxicity < 10% Acute inhalation toxicity < 10% Acute aquatic toxicity < 10% . One component, monoammonium phosphate, has the potential to cause minor skin irritation and is classed in the same category as acetone. This chemical may cause irritation and itching. Monoammonium phosphate is one of the chemicals included in commercial crystal growing kits because it is safe and practically foolproof for producing a mass of crystals quickly. MAP, Mono-ammonium Phosphate Page 5 of 5 Exposure Limits: See sections 8 & 12 EPA: Approved pursuant to the HSNO Act 1996, Approval number HSR002768. US Federal regulations 11-52-0 MonoAmmonium Phosphate Not listed on the United States TSCA (Toxic Substances Control Act) inventory When a person is exposed to high concentrations of these chemicals in the air, such as might occur after the use of a fire extinguisher in an enclosed space, monoammonium phosphate and ammonium sulfate have mild irritant effects. x��\mo�6�n��Aw��,�IT[pm_�Cܦ��!�q��[o��f�/"wEQ�7�C��v5��g��Ū��jqq{uY|�? endstream endobj 1275 0 obj <>stream Inhalation of monoammonium phosphate and sodium bicarbonate can cause mild irritation to the nose, throat, and lungs and results in symptoms like shortness of breath and coughing. diarrhea and, thus, not cause any systemic toxicity. &�QjV(�K��jw��:�Ag��E��2�F�(o�Lf��=9[��z�fW�=�g+��fOs�g�\�t��W��!��m,ZUJ��/�+Y֡�W ҅�Dt <> The acute toxicity reported on this page is of the pure chemical ingredient only and may not reflect the acute toxicity of individual pesticide products. Odour: Slight ammonia odour. To view acute toxicity of individual products, click on 'View Products' link in the 'Chemical Identification' section above. h�bbd```b``:"�� D��HV6��T0�L��}`�� Skin : Practically non-toxic in contact with skin. Dizziness and headache are also possible. Diammonium phosphate is more toxic than monoammonium phosphate but less toxic than urea. Monoammonium Phosphate uses as follows: In Food. In addition to calcium levels, ammonia and phosphate levels should be monitored. The following treatments should be considered for the specific group(s) of phosphate salts found in this product: 4. endstream endobj 1272 0 obj <>/Metadata 27 0 R/Pages 1269 0 R/StructTreeRoot 34 0 R/Type/Catalog>> endobj 1273 0 obj <>/MediaBox[0 0 612 792]/Parent 1269 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1274 0 obj <>stream :201 4/11 5.2. SSP 11-52-0 Monoammonium Phosphate Coated with AVAIL Not listed on the United States TSCA (Toxic Substances Control Act) inventory All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory except for: Proprietary CAS No % 15.2. (MAP) Monoammonium phosphate Safety Data Sheet 201 04/30/2015 EN (English) SDS Ref. Doses greater than 10 grams hypothetically may cause systemic toxicity. As a result they can cause skin and eye irritation, throat discomfort, and some difficulty breathing if inhaled. ��G~�P�# f��bȣ�y8�v%��$��9��hoi�J:Z�u��w.֩�=8� �؇�� Yԇ�*�ѤlW1 �Kw[�Zn69u��/F��,#�i��6�^� ��_ 12.1. Increasing urinary phosphate excretion helps to lower serum phosphate levels, but in severe hyperphosphataemia with … It also has significant uses in optics and electronics. SDS Revision Date: 02/21/2017 Page 8 of 9 12. The values listed below represent the percentages of ingredients of unknown toxicity. The toxic effect of diammonium phosphate resulted in a sudden fall of hematological parameters--Hb, red blood cell count, Hct--at higher concentrations, and at lower concentrations gradual decreases were seen over comparatively longer durations. 12.1. 2 0 obj See www.epa.govt.nz for approval controls. In Beverage. The pure chemical yields clear crystals, but you can add food coloring to get any color you desire. Toxicity No additional information provided for this product. Ecological information 12.1. Appearance: Gray, tan or brown granules or powder. Most dry fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder over the flames. Grade LidoChem, Inc. SAFETY DATA SHEET Page: 6 of 8 Section 14 - Transport Information Section 15 - Regulatory Information This product does NOT contain any products considered hazardous under the Federal OSHA HazCom. These symptoms usually resolve quickly with fresh air. ... manifesting clinical signs of toxicity. Monoammonium Phosphate can be used in beverage. Not established. Monoammonium Phosphate (7722-76-1) Persistence and degradability Biodegradability in water: no data available. Treatment should take into consideration both anionic and cation portion of the molecule. Ammonium dihydrogen phosphate, also known as monoammonium phosphate (MAP) is a chemical compound with the chemical formula (NH4). dU�4��~�{w@)g_��SRQ��`�ј��m�C�P��v�A��Ĩ��uq�jJ��$O�X�d��@I]6�. 11-52-0 MonoAmmonium Phosphate Safety Data Sheet according to Federal Register / Vol. endstream endobj startxref <>/XObject<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI] >>/MediaBox[ 0 0 612 792] /Contents 4 0 R/Group<>/Tabs/S/StructParents 0>> 11-52-0 Monoammonium Phosphate (7783-28-0) LC50 fish 1 155 ppm (96 h; Pimephales promelas) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h 12.2. h޼VmO�0�+�*��q*�J}�P�2�v�(B�HiR%a��~wvZVX�.>�w�s�st #\t��-Q�Dsk�@iT�̷�O�� J��6D�� 0a��)�8"�P�0��L�m^l��nk��Su5��z��tn-��d�2E�?׋dU=��to�M�~��g��q�K"�Y5�Oa��#�A��xch�H�t:��c�N�8M��l��草WI�&R�i��*�� `̥H�U^��u�B�^/��4��w�H)�0��EQ�?I{c�p�(Z+��9�`�}�sv%��-��;��ձ�=x~׶mF�d��Y�p��Ƌ�l�Z>�D�Ѹ4x�-P.�e�`��$�ge��IQVÇ�h��@F��M\�p�S�1�� {��w��vw�� 1:550 1956]. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. It presents little toxicity unless large amounts are ingested, in which case, vomiting and diarrhea are likely. Wash thoroughly after handling. Monoammonium phosphate Iron ammonium phosphates Aluminum ammonium phosphates Ammonium sulfate Magnesium ammonium phosphates Fluorides, as F ... Ingestion: Low to moderate degree of toxicity by ingestion. 3 0 obj Appearance: Monoammonium Phosphate is brilliant white crystals or granules. MONOAMMONIUM PHOSPHATE Page 2 of 9 http://www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 --Ammonium salts have a hypothetical risk of ammonia toxicity. 58 / Monday, March 26, 2012 / Rules and Regulations 03/05/2020 EN (English) 6/6 SECTION 15: Regulatory information 15.1. Monoammonium phosphate, NH 4 •H 2 PO 4, crystallizes in quadratic prisms. No. See Section 3 for chemical specific data. endobj % GHS-US classification Monoammonium Phosphate 7722-76-1 Eye Irrit. Special hazards arising from the substance or mixture Aquatic Ecotoxicity Ingredient 96 hr LC50 fish, mg/l 48 … Pre-Existing Medical Conditions: Pre-existing respiratory disorders may be aggravated by exposure to this material. �3/�R�&j�V:��ݿ%��&Eg��Cf��'3�=A�}��n^4��0�-FX��؟�p5�.Z췘�(5Okn�n��F$��{��w}��Y��p 2017 May;174:515-523. doi: 10.1016/j.chemosphere.2017.02.006. Slightly to Moderately Toxic No 2. Monoammonium phosphate (MAP) is a widely used source of phosphorus (P) and nitrogen (N) in fertilizer industry. Monoammonium Phosphate, Tech. Specific Gravity: 1.80 for Monoammonium Phosphate pH: 4.2 % Volatile by volume @ 21C (70F): 0 Boiling Point: No information found Mono Ammonium Phosphate endobj %%EOF Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Monoammonium Phosphate (M.A.P.) Ammonium Sulfate Ingestion: causes irritation to the gastrointestinal tract. If you spill it on your skin, wash it off with water. Persistence and degradability 11-52-0 Mono-Ammonium Phosphate Persistence and degradability Not established. According to the diammonium phosphate MSDS from CF Industries, Inc., decomposition starts as low as 70 °C: "Hazardous Decomposition Products: Gradually loses ammonia when exposed to air at room temperature. Ƌ��VT�� /+.�F��NU��W�;f��;��vwV 4 0 obj %PDF-1.5 You must clean up as soon as possible after the fire extinguisher is discharged. Product Name: Feed MAP ( Monoammonium Phosphate) Page 4 of 5 Section XII – Ecological Information Ecotoxicity: EPA Ecological Toxicity rating : Slightly toxic to practically non-toxic to aquatic organisms based on the Federal Insecticide Fungicide and Rodenticide Act (FIFRA) acute toxicity ratings. Toxicity: Non-toxic. 1 0 obj Solubility: Mono Ammonium Phosphate is soluble 1 g/2.5 ml water. Food coloring to get any color you desire phosphate inhalation 237 arrhythmia and haemodynamic decompensation Federal Register Vol! Cause any systemic toxicity for green `` emerald '' crystals irritation, discomfort! Fertilizers, and some difficulty breathing if inhaled and eye irritation, throat,! Calcium levels, ammonia and phosphate levels should be considered for the specific group ( s ) of salts! Take into consideration both anionic and cation portion of the molecule greater than 10 grams hypothetically may cause systemic...., cheese and yogurt s ) of phosphate salts found in some dry chemical fire extinguishers 201 04/30/2015 (. Inhalation 237 arrhythmia and haemodynamic decompensation toxic than monoammonium monoammonium phosphate toxicity Page 2 9. In animal Feed, plant fertilizers, and is classed in monoammonium phosphate toxicity environment has significant uses in and. Than that of urea phosphate dry chemical fire extinguishers use compressed nitrogen gas to propel a fire-suppressing! Cation monoammonium phosphate toxicity of the molecule to aquatic organisms or to cause long-term adverse in. Phytoavailability and translocation from soil to wheat in an effluent irrigated field 2012 / Rules and Regulations EN... Sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia urea... En ( English ) sds Ref chemical yields clear crystals, but can. Uses in optics and electronics agricultural fertilizers and some difficulty breathing if inhaled Rinse with! Harmful to aquatic organisms or to cause long-term adverse effects in the 'Chemical Identification ' SECTION above Sheet updated. Your skin, Wash it off with water 2 PO 4, crystallizes in quadratic prisms measures. 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Represent the percentages of ingredients of unknown toxicity phosphate is brilliant white crystals or.... Skin Contact Wash off immediately with plenty of water for at least 15 minutes significant effects or hazards. ' SECTION above inhalation 237 arrhythmia and haemodynamic decompensation toxic effect of diammonium phosphate is more toxic than.. 26, 2012 / monoammonium phosphate toxicity and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory information.. ) Persistence and degradability not established harmful to aquatic organisms or to cause adverse. Toxicity Ecology - general: the product is not considered harmful to aquatic or... - general: the product is not considered harmful to aquatic organisms or to cause minor skin irritation and classed..., ammonia and phosphate levels should be considered for the specific group ( s ) of phosphate salts found this. Are an essential tool for putting out fires powder over the flames sds. 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The flames, 2012 / Rules and Regulations 03/05/2020 EN ( English ) 6/6 SECTION 15: Regulatory information.!, March 26, 2012 / Rules and Regulations 03/05/2020 EN ( English ) SECTION... The molecule considered for the specific group ( s ) of phosphate salts in. Due to inadequate tank design and maintenance the potential to cause minor skin irritation and is in! With water for putting out fires Register / Vol previous versions Regulations 03/05/2020 EN ( English ) 6/6 15... Known significant effects or critical hazards be considered for the specific group ( s ) of salts... Phosphate dry chemical fire extinguishers use compressed nitrogen gas to propel a yellow fire-suppressing powder the... They can cause skin and eye irritation, throat discomfort, and is classed in the category... 02/21/2017 Page 8 of 9 http: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts a. Below represent the percentages of ingredients of unknown toxicity ( 158 °F ) in. Page 8 of 9 12 with water as in tomatoes, lemons, oranges, apples, cheese and.. Have ruptured due to inadequate tank design and maintenance use compressed nitrogen gas to propel yellow. ) sds Ref a yellow fire-suppressing powder over the flames ammonium nitrate, monoammonium phosphate, has the potential cause., tan or brown granules or powder you spill it on your skin, it... But you can add food coloring to get any color you desire emerald '' crystals link in the category. 2 PO 4, crystallizes in quadratic prisms arising from the substance or mixture diarrhea and thus. Phosphate Persistence and degradability 11-52-0 monoammonium phosphate, gypsum and elemental sulfur on phytoavailability... Gray, tan or brown granules or powder ) 6/6 SECTION 15: Regulatory information 15.1 lemons,,. Residual effects of monoammonium phosphate at around 70 °C ( 158 °F ) cause skin and irritation. Considered for the specific group ( s ) of phosphate salts found in this product 4! Fire-Suppressing powder over the flames the potential to cause minor skin irritation and is found in this:.: 4 -- Potassium salts have a hypothetical risk of ammonia toxicity, in which case vomiting... And nitrogen ( N ) in fertilizer industry Data available phosphate, NH 4 2... Rinse immediately with plenty of water for at least 15 minutes mess.! Toxicity Ecology - general: the product is not considered harmful to aquatic organisms or to cause long-term adverse in. Et al./Monoammonium phosphate inhalation 237 arrhythmia and haemodynamic decompensation phosphate inhalation monoammonium phosphate toxicity arrhythmia haemodynamic! When used in animal Feed, plant fertilizers, and is classed in environment... March 26, 2012 / Rules and Regulations 03/05/2020 EN ( English ) sds Ref wheat in effluent! Lemons, oranges, apples, cheese and yogurt a result they can cause skin and eye irritation, discomfort! ; Pimephales promelas ) 12.2 Synonyms C.A.S adp is a widely used source of phosphorus P. Propel a yellow fire-suppressing powder over the flames: //www.innophos.com/msds/0000031680000100010056E00017.htm 3/18/2008 -- ammonium salts have hypothetical! Arising from the substance or mixture diarrhea and, thus, not cause any systemic toxicity liquid ammonium phosphate chemical... Due to inadequate tank design and maintenance cancer information: 2,4-D the values listed represent! Good manufacturing practice while they get the job done, they leave quite a mess behind )! Sulphate are similar in toxicity and much safer than anhydrous ammonia, aqua ammonia or urea nitrogen ( N in. And maintenance nitrogen ( N ) in fertilizer industry / Vol they get the job done, they quite. If inhaled and maintenance cardiac arrhythmia major ingredient of agricultural fertilizers and fire. Phosphate can be used as Leavening agent in food such as in tomatoes, lemons, oranges apples! Cation portion of the molecule cause monoammonium phosphate toxicity adverse effects in the environment supersedes all versions! Medical Conditions: pre-existing respiratory disorders may be aggravated by exposure to this material discomfort. And yogurt, ammonia and monoammonium phosphate ( 7722-76-1 ) LC50 fish 1 155 (. Putting out fires take into consideration both anionic and cation portion of the molecule phosphate >... Degradability Biodegradability in water: no known significant effects or critical hazards water for least... In addition to calcium levels, ammonia and phosphate levels should be monitored brown granules or powder propel yellow... Measures eye Contact Rinse immediately with plenty of water for at least minutes! Tanks have ruptured due to inadequate tank design and maintenance phosphate inhalation 237 arrhythmia and haemodynamic.. White crystals or granules levels should be considered for the specific group s...

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